材料科学
复合材料
电磁屏蔽
渗流阈值
多孔性
导电体
渗透(认知心理学)
聚合物
碳纳米管
电阻率和电导率
生物
电气工程
工程类
神经科学
作者
Yilong Li,Danyang Song,Quanpeng Chen,Yujie Liu,Yingjuan Zheng,Cong Nie,Yunchao Jia,Hongjuan Zheng,Fengchun Wei
摘要
Abstract Conductive network built by less conductive filler is vital for high‐performance conductive polymer composites. Herein, porous ultrahigh molecular weight polyethylene (UHMWPE)/poly(vinylidene fluoride) (PVDF) blends filled with multi‐walled carbon nanotubes (MWCNT) were fabricated, where poly(lactic acid) (PLA) and polymethyl methacrylate (PMMA) were served as sacrificial template. An interconnecting conductive network is formed based on the UHMWPE segregated structure and PVDF co‐continuous structure in porous UHMWPE/PVDF/MWCNT (UFC) composites. The UFC composites demonstrate a low electrical percolation threshold (0.25 wt%) due to the segregated/co‐continuous structure. Porous UFCs exhibit higher electromagnetic interference shielding effectiveness (EMI SE) than their compact counterparts. The blend‐templated porous structure enhances the EMI SE of composites because a well‐dispersed and densely packed MWCNT network is formed around the polymer particles, facilitating the multiple reflections of electromagnetic waves inside the composites. This effort provides a facile way for preparing high‐performance shielding materials by controlling the hierarchical structure and conductive filler distribution. Highlights Hierarchical porous structure was constructed by blend sacrificial templating method. Carbon fillers are exclusively distributed at blend interface, forming the segregated structure. Porous composites exhibit better shielding performances than their solid counterparts.
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