化学
催化作用
脱羧
有机化学
偶联反应
羧酸
钯
组合化学
出处
期刊:Chinese Journal of Organic Chemistry
[Shaghai Institute of Organic Chemistry]
日期:2015-01-01
卷期号:35 (5): 984-984
被引量:17
标识
DOI:10.6023/cjoc201409029
摘要
Since carboxylic acids have distinguishing features of non-toxicity, low cost, ready availability and easy storage, Pd-catalyzed decarboxylative coupling reactions of (hetero)aromatic carboxylic acids have been obtained rapid development since this century, and have exhibited a tendency toward replacement of traditional coupling reactions.The coupling reactions of Pd-catalyzed decarboxylation of aromatic carboxylic acids with various substrates of olefins, aryl halides, arenes, aryltrifluoroborates and etc. are reviewed, and the relevant reaction mechanisms are discussed.
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