Direct numerical simulations of high-enthalpy supersonic turbulent channel flows including finite-rate reactions

Direct numerical simulations of temporally evolving high-enthalpy supersonic turbulent channel flows are conducted at a Mach number of 3.0 and Reynolds number of 4880 under isothermal wall conditions. Air is assumed to behave as a five-species mixture, and chemical non-equilibrium and equilibrium assumptions are adopted to investigate the influence of finite-rate reactions on the turbulent statistics and large-scale structures. The two wall temperatures of 1733.2 and 3500 K are such that the mixture components undergo strong dissociation and recombination reactions along the channel. Investigation shows that the turbulent intensity is weakened and the mean and fluctuating temperatures are smaller when finite-rate reactions are considered. The mean dissociation degree is a quadratic function of the normal position, and its curvature under the chemical non-equilibrium assumption is greater than that under the chemical equilibrium assumption. The fluctuating mass fractions of the generated species seem to decrease slightly in the near-wall region, and their distributions are obviously different from those of the fluctuating velocity and fluctuating temperature. Finite-rate reactions increase the proportion of turbulent kinetic energy production in the skin friction decomposition, especially when the wall temperature is 3500 K. The large-scale structures visualized by the cross correlation between temperature and species mass fraction become stronger in the normal direction. The turbulent Schmidt number and several velocity–temperature correlations, including the recovery enthalpy and strong Reynolds analogy, are insensitive to the chemical reaction rate and wall temperature.