Facile Fabrication of Amorphous Photonic Structures with Non-Iridescent and Highly-Stable Structural Color on Textile Substrates

Amorphous photonic structures with non-iridescent and highly-stable structural color were fabricated via a simple one-step spray-coating technique. With this strategy, the obtained films on textile substrates presented short-ordered and amorphous photonic structures (APSs) similar to the amorphous nanostructures of avian feathers. The structural color presented the same hue when viewed at different angles and could be well controlled by varying the diameters of the SiO₂ nanospheres. The prepared fabrics with structural color exhibited high color stability due to stability in both the assembled physical structure and the refractive index. The high stability of the assembled physical structure was attributed to the cementing effect of Poly(methylmethacrylate-butylacrylate) P(MMA-BA) existing between textile substrate and SiO₂ nanospheres and among SiO₂ nanospheres, while the high stability in the refractive index was contributed by the liquid-resistance achieved by both the surface roughness and the low-surface-energy of the as-sprayed APSs. With the resistances to external forces and liquid invasion, the non-iridescent brilliant structural color of the as-prepared fabrics could be kept steady. In this study, an approach of fabricating APSs with non-iridescent and stable structural color was established to enhance its potential application in structural coloration of textiles, and other color-related smart textiles. .