Recent developments in MIL-101 metal organic framework for heterogeneous catalysis

Abstract Metal organic frameworks (MOFs) are currently gaining considerable attention as heterogeneous catalysts. Since the functionality of the framework and the pore size of the MOFs can be adjusted over a wide range for various catalytic reactions, the usage of these materials as solid catalysts is attractive. One of the preferred catalytic mesoMOFs is MIL-101 (MIL: Material of Institute Lavoisier) family which has been mainly investigated. The large surface area, high pore volumes, and acceptable solvent/thermal stability (MIL-101(Cr) up to 300 °C) have led the MIL-101 family to be considered an ideal and widespread MOF for use as a great heterogeneous catalyst or solid support for a variety of reactions. The objective of this review is to present recent research on the use of the MIL-101 family for heterogeneous catalysis in gas and liquid phase reactions.