Study on power generation and Congo red decolorization of 3D conductive PPy-CNT hydrogel in bioelectrochemical system

In this paper, a polypyrrole-carbon nanotube hydrogel (PPy-CNT) with 3D macroporous structure was prepared by secondary growth method. This self-supporting material with good conductivity and biocompatibility can be directly used as anode in a microbial fuel cell (MFC). The prepared material had a uniform structure with rich 3D porosity and showed good water retention performance. The effect of the mass ratio of PPy and CNT in the hydrogel were also investigated to evaluate the electrical performance of MFC. The MFC with 10:1 PPy-CNT hydrogel anode could reached the maximum power density of 3660.25 mW/m3 and the minimal electrochemical reaction impedance of anode was 5.06 Ω. The effects of Congo red concentration, external resistance and suspended activated sludge on decolorazation and electricity generation were also investigated in the MFC with the best performance hydrogel. When the Congo red concentration was 50 mg/L and the external resistance was 200 Ω, the dye decolorization rate and chemical oxygen demand (COD) removal rate could reach 94.35% and 42.31% at 48h while the output voltage of MFC was 480 mV. When activated sludge was present, the decolorization rate and COD removal rate could be increased to 99.55% and 48.08% at 48 h. The above results showed that the porous hydrogel anode had broad application prospects in synchronous wastewater treatment and electricity production of MFC. • A 3 D porous, self-supporting hydrogel anode was successfully synthesized. • The biocompatibility and mechanical property of anode was improved by adding CNT. • The maximum power density of MFC equipped with PPy-CNT anode reached 3660.25 mW/m 3 . • MFC produced electricity and decolorized Congo red, synchronously.