纳滤
聚丙烯腈
氢氧化物
膜
超滤(肾)
戊二醛
化学
膜技术
化学工程
水溶液
萃取(化学)
色谱法
无机化学
工程类
有机化学
生物化学
聚合物
作者
Hongxu Ni,Naixin Wang,Yuye Yang,Mengxin Shen,Quan‐Fu An
出处
期刊:Desalination
[Elsevier]
日期:2023-02-01
卷期号:548: 116256-116256
被引量:16
标识
DOI:10.1016/j.desal.2022.116256
摘要
As an important resource, lithium is abundant in Salt Lake. The high Mg2+/Li+ ratio is the main obstacle to lithium extraction. Positively-charged nanofiltration membrane has shown great potential in the separation of Mg2+/Li+. Herein, we report a facile method to construct positively-charged nanofiltration membrane by polyethyleneimine (PEI) and layered double hydroxide (LDH) nanosheets on hydrolyzed polyacrylonitrile ultrafiltration membrane. Subsequently, the PEI-LDH composite membrane was crosslinked with glutaraldehyde (GA) to improve its stability. The incorporation of LDH could improve the positive charge of the membrane. Then, the obtained PEI-LDH/GA membrane showed an enhanced separation performance for separating Mg2+/Li+ in an aqueous solution. When the Mg2+/Li+ ratio was 10, the membrane showed a separation factor (SMg2+/Li+) of 18.7. Moreover, the membrane could maintain the separation performance for 100 h, which exhibited a potential application in Mg2+/Li+ separation.
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