Synergistic mechanisms of carbon-based materials for VOCs photocatalytic degradation: A critical review

With the rapid expansion of human activities, there has been a significant increase in the release of volatile organic compounds (VOCs) from factories and interior decoration materials, posing a substantial risk to the surrounding ecosystem and human health. Photocatalysis technology based on semiconductors has emerged as a promising solution for mitigating atmospheric pollution and indoor air quality concerns. However, single semiconductors encounter several challenges when it comes to VOC photodegradation, including issues like the weak adsorption capacity for VOC molecules, insufficient surface-active sites, and limited light utilization. In recent decades, carbon-based materials have gained considerable interest in photodegrading VOCs owing to their strong adsorption capacity, electrical conductivity, broad light absorption range, and tunable surface characteristics. The incorporation of carbon materials can enhance the photodegradation efficiency of VOCs by facilitating the transfer of VOCs from the ambient air to the surface of the photocatalysts, increasing the number of active surface sites, expanding the light absorption region, and promoting the separation of charge carriers. This review provides a comprehensive overview of the applications of carbon materials with different dimensions in enhancing the performance of semiconductors for the photocatalytic degradation of VOCs. Based on the fundamental principles of photocatalytic VOC degradation, this review explores the factors influencing the degradation performance of catalysts and elucidates the degradation mechanisms. Moreover, it summarizes a range of synthesis approaches for carbon-based photocatalysts, discussing the multiple roles played by carbon materials in these processes. In conclusion, the review offers insights into the current state of carbon-based photocatalysts and outlines the existing challenges. It also provides a perspective on the future development of these materials, highlighting the need for continued research and innovation in this field.