钝化
钙钛矿(结构)
材料科学
甲脒
钙钛矿太阳能电池
碘化物
能量转换效率
氢
氮气
太阳能电池
无机化学
光化学
化学工程
纳米技术
光电子学
化学
有机化学
图层(电子)
工程类
作者
Geping Qu,Ying Qiao,Jie Zeng,Siyuan Cai,Qian Chen,Deng Wang,Danish Khan,Limin Huang,Baomin Xu,Jiangzhao Chen,Tarek H. El‐Assaad,Yang‐Gang Wang,Dominic V. McGrath,Zong‐Xiang Xu
出处
期刊:Nano Energy
[Elsevier]
日期:2023-12-01
卷期号:118: 108974-108974
标识
DOI:10.1016/j.nanoen.2023.108974
摘要
Perovskite defect passivation has been researched extensively as an essential technique to improve the efficiency and stability of perovskite solar cells (PSCs) and thus drive their future commercialization. Three phthalocyanines named NP-SC6-ZnPc, NP-SC6-CuPc, and NP-SC6-H2Pc were synthesized and use for PSCs passivation. Theoretical calculations and experimental verifications confirmed that NP-SC6-H2Pc had the best passivation effect on perovskites. The phthalocyanine ring’s central hydrogen atoms are transferred dynamically from NP-SC6-H2Pc and interact with the formamidinium lead iodide (FAPbI3) perovskite through nitrogen-hydrogen bonding, resulting in α-FAPbI3 perovskite formation and increasing the sulfur/nitrogen (S/N) passivation capability. FAPbI3-based PSCs treated with NP-SC6-H2Pc demonstrated the highest power conversion efficiency (PCE) of 24.03% (certified PCE of 23.78%) with excellent stability. This significant finding represents the first observation of dynamic transfer of the hydrogen atoms in phthalocyanine and provides a thorough investigation of the perovskite passivation mechanism.
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