化学
路易斯酸
催化作用
硅醇
核磁共振波谱
镓
分子
反应性(心理学)
吡啶
脱氢
固态核磁共振
结晶学
立体化学
有机化学
核磁共振
医学
物理
替代医学
病理
作者
Scott R. Docherty,Laura A. Völker,Alexander V. Yakimov,René Verel,Christophe Copéret
标识
DOI:10.26434/chemrxiv-2023-mp1r9-v2
摘要
Determining the structure of Ga surface sites in Ga-based materials, used in catalysis, is critical for understanding their reactivity. However, obtaining molecular-level insights into their structure remains challenging. Here, using solid state Nuclear Magnetic Resonance (NMR) spectroscopy (71Ga, 31P and 15N), two different families of acid sites are identified in a gallosilicate material (Ga@SiO2), prepared via Surface Organometallic Chemistry and used as an efficient heterogeneous propane dehydrogenation catalysts or catalyst support. Through probe molecule studies using pyridine (Py) and triphenylphosphine oxide (TPPO), coupled with the synthesis of well-defined molecular analogs of surface sites and computational modelling on related cluster models using density functional theory, the Ga NMR signatures and the molecular structure of two types of sites, namely Brønsted acid sites and Lewis acid sites, are identified. These tetra-coordinate sites can be described as Ga sites bound to three anionic siloxide surface ligands along with a silanol or a siloxane bridge, respectively, each associated with specific NMR parameters, which change markedly upon interaction with Py or TPPO, thereby enabling their structural characterization.
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