Few‐layer Graphene Lithiophilic and Sodiophilic Diffusion Layer on Porous Stainless Steel as Lithium and Sodium Metal Anodes

Abstract In order to subdue the obvious problem of uneven electric field distribution on regularly used copper/aluminum current collectors for alkali metal batteries, graphene on porous stainless steel (pSS_Gr) was fabricated using the ion etching technique that is employed as an effective host for lithium and sodium metal anodes. The binder‐free pSS_Gr demonstrated stable Li plating and stripping at areal current and capacity of 6 mA cm −2 and 2.54 mAh cm −2 , respectively, for over 1000 cycles with 98% coulombic efficiency (C.E.). Also, in the case of Na metal anode, the host has shown stable performance at 4 mA cm −2 and 1 mAh cm −2 over 1000 cycles with ∼100% C.E.. Further, a full cell composed of Li‐plated pSS_Gr as an anode and LiFePO 4 as a cathode is electrochemically tested at 50 mA g −1 current density with stable 100 cycles.