荧光粉
材料科学
共发射极
色域
光电子学
显色指数
场电子发射
光学
电子
量子力学
物理
作者
Weijie Zhou,Yiyi Ou,Lin Huang,Enhai Song,Fengkai Ma,Zhiguo Xia,Hongbin Liang,Qinyuan Zhang
标识
DOI:10.1002/adma.202206278
摘要
Abstract Transparent displays (TDs) rendering “levitating” images on screen have appeared as an emerging technology toward augmented/mixed reality applications. However, the traditional phosphor design and screen construction have severely limited the TD performance owing to the lack of efficient narrow‐band blue emitters and stable screen structure. Herein, the novel narrow‐band (full width at half maximum: 32 nm) NaLi 3 SiO 4 :Eu 2+ phosphor with a peak at 467 nm as a key blue emitter is explored, and it is sandwiched in layered film as a unique screen design. The devised screen features decent transparency, high emission color purity, and good reliability, and the TD prototype renders “floating” static images and vivid animation with broad viewing angle (15°–165°) and large color gamut (97% of National Television Standards Committee). Spectroscopic and microstructural characterizations reveal the TD superior performance originates from synergistic contributions of moderate crystal field effect (ε c ≈ 1.13 eV; ε cfs ≈ 1.60 eV), weak vibronic coupling ( S ≈ 3; ħω ≈ 285 cm −1 ), and limited thermal ionization of 5d electrons ( E a ≈ 0.43 eV) for NaLi 3 SiO 4 :Eu 2+ emission and layered architecture for screen film. These findings establish fundamental guidelines for narrow‐band emitting materials design and shine light on superior TD innovative development.
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