材料科学
接触角
硅烷化
表面粗糙度
埃洛石
嫁接
复合材料
生物污染
化学工程
莲花效应
衰减全反射
表面光洁度
织物
傅里叶变换红外光谱
原材料
有机化学
化学
工程类
膜
聚合物
生物化学
作者
Namrata V. Patil,Anil N. Netravali
标识
DOI:10.1002/adsu.201900009
摘要
Abstract This paper presents a sustainable biomimetic approach to create ultrahydrophobic cotton fabrics. Cotton fabrics are modified using biobased raw materials to create multiple scale roughness and low surface energy on their surfaces. Naturally occurring halloysite nanotubes (HNT) are modified by silanization and direct assembly of silica (SiO 2 ) nanospheres on the surface of HNTs. HNTs “decorated” with SiO 2 nanospheres are covalently bonded onto the surface of cotton fabrics, creating a durable multiple scale surface roughness. Surface modified cotton fabrics are further grafted with fatty acid without using any solvent, via esterification. The combination of the hierarchical roughness pattern created on the surface through modified HNT, and fatty acid treatment results in ultrahydrophobic fabrics with water contact angles (WCAs) above 150°. Surface topographies of modified HNT particles and chemical changes are fully characterized. Attenuated total reflectance Fourier‐transform infrared and WCA studies are used to confirm the grafting of modified HNT particles and aliphatic fatty chains on surface of fabrics. The ultrahydrophobic cotton fabrics washed for five standard laundry cycles (25 home washings) show that the ultrahydrophobicity is durable. Moreover, the ultrahydrophobic fabrics are oleophilic, making them suitable for use in oil–water separation, anti‐biofouling and packaging, and other applications apart from water repellent clothing.
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