化学
劈理(地质)
键裂
碳纤维
区域选择性
增强碳-碳
反应性(心理学)
碳-碳键
双加氧酶
氧化裂解
氧化磷酸化
有机化学
酶
催化作用
生物化学
复合材料
病理
工程类
岩土工程
材料科学
替代医学
复合数
医学
断裂(地质)
作者
Caleb J. Allpress,Lisa M. Berreau
标识
DOI:10.1016/j.ccr.2013.06.001
摘要
Over the past decade, several metalloenzymes have been characterized which catalyze dioxygenase-type aliphatic carbon–carbon bond cleavage reactions. The substrates for these enzymes vary from species that are stable with respect to O2 under ambient conditions, to examples that in anionic form exhibit O2 reactivity in the absence of enzyme. Described herein are advances from studies of the enzymes themselves and model systems. These combined investigations provide insight into novel mechanistic pathways leading to aliphatic carbon–carbon bond cleavage and/or the factors that influence regioselectivity in the oxidative carbon–carbon bond cleavage reactions.
科研通智能强力驱动
Strongly Powered by AbleSci AI