零价铁
硫化
硝酸盐
化学
无机化学
可渗透反应墙
环境化学
吸附
环境修复
硫黄
污染
有机化学
生态学
生物
作者
Hejie Qin,Xiaohong Guan,Paul G. Tratnyek
标识
DOI:10.1021/acs.est.9b02419
摘要
Competition among oxidizing species in groundwater and wastewater for the reductive capacity of zerovalent iron (ZVI) makes the selectivity of ZVI for target contaminant degradation over other reduction pathways a major determinant of the feasibility of ZVI-based water treatment processes. The selectivity for reduction of contaminants over water is improved by sulfidation, but the effect of sulfidation on other competing reactions is not known. The interaction between these competing reactions was investigated using N-nitrosodimethylamine (NDMA) as the target contaminant, nitrate as a co-contaminant, and micrometer-sized ZVI with and without sulfidation. Unsulfidated ZVI reduced NDMA to dimethylamine via N,N-dimethylhydrazine, but the addition of nitrate decreased the rate of NDMA reduction and increased the quantity of intermediate observed. With sulfidated ZVI, the kinetics and products of NDMA reduction were similar to those with unsulfidated ZVI, but no inhibitory effect of nitrate was observed. Conversely, the reduction of nitrate-which dominated NDMA reduction in unsulfidated ZVI systems-was strongly inhibited by sulfidation. H2 and Fe2+ generation by sulfidated ZVI was almost independent of nitrate concentration. Therefore, sulfidation improved the efficiency of NDMA reduction by ZVI in the presence of nitrate mainly by inhibiting nitrate reduction. The shift in selectivity of ZVI for NDMA over nitrate upon sulfidation was due to replacement of Fe0/FexOy surface sites with FeS.
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