电化学
降级(电信)
电极
材料科学
阳极
镍
阴极
选择性
氧化还原
化学工程
无机化学
化学
催化作用
冶金
物理化学
有机化学
工程类
电信
计算机科学
作者
Tianyi Wu,Xiangang Kong,Siyuan Tong,Chunlei Yu,Jia Liu,Yang Tang,Xinjiletu Yang,Yongmei Chen,Pingyu Wan
标识
DOI:10.1016/j.apsusc.2019.05.358
摘要
Degradation of NO3− into harmless N2 is a significant challenge in the field of water treatment. In this work, 3D self-supported hierarchical electrode composed of ultra-thin Cu nanosheets-assembled micro-columns on porous nickel foam (Cu NSs/NF) was prepared by three steps, including electrodeposition of CuCl-Cu, thermal oxidation into CuCl-CuO and electrochemical reduction into Cu NSs. Benefitting from the advantages of large surface area and highly active interface as well as fast electron-transfer path, Cu NSs/NF exhibits the significant positive-shift of potential and higher current density than other Cu-based electrodes in the electrochemical reduction of NO3− (NO3−-ER). Not only that, an extremely high sensitivity of nitrate reduction response up to 11.23 mA mM−1 cm−2 was obtained by chronoamperometric test, which is much higher than those of previously reported works. Moreover, a conversion percentage of 99.7% for NO3−-ER was achieved on Cu NSs/NF cathode in NO3−-ER experiments. Finally, through the cathodic reduction of NO3− coupled with the anodic oxidation of Cl−, and the subsequent chemical reaction of NH4+ and ClO−, the highly efficient degradation of NO3− into N2 with selectivity as high as 97.2% was realized. This work provides a highly efficient Cu NSs/NF electrode and a promising way for degradation of NO3− into N2.
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