催化作用
选择性
漫反射红外傅里叶变换
傅里叶变换红外光谱
贵金属
多相催化
甲醛
化学
核化学
无机化学
化学工程
光催化
有机化学
工程类
作者
Ke Liu,Zhuofeng Zhao,Weiwei Lin,Qiang Liu,Qifan Wu,Ruizhi Shi,Chao Zhang,Haiyang Cheng,Masahiko Arai,Fengyu Zhao
出处
期刊:Chemcatchem
[Wiley]
日期:2019-05-20
卷期号:11 (16): 3919-3926
被引量:19
标识
DOI:10.1002/cctc.201900582
摘要
Abstract A non‐noble heterogeneous catalyst of Cu/TiO 2 was prepared for N ‐methylation of N ‐methylaniline (MA) with CO 2 and H 2 . 5 wt.–% Cu loaded TiO 2 (P25) catalyst exhibited a high performance, with 82 % MA conversion and 98 % N,N ‐dimethylaniline (DMA) selectivity under the reaction conditions used (4 MPa H 2 , 2 MPa CO 2 , 180 °C, 36 h). The Cu/TiO 2 catalyst was more effective with respective to the total conversion and the DMA selectivity as compared to 5 wt.–% Cu loaded catalysts on CeO 2 , ZnO and activated carbon materials. The possible active species of Cu/TiO 2 catalyst should be both Cu + and Cu 0 which contributed to the high activity as the reaction conversion increased linearly with them exposed on the surface of catalyst. Moreover, the reaction pathways involved were studied; it was likely that the reaction took place via an intermediate of formaldehyde that was formed from CO 2 and H 2 , as confirmed by in situ diffuse reflectance Fourier‐transform infrared spectroscopy, then it reacted with MA to give N ‐methylformanilide (MFA), and finally MFA was hydrogenated to DMA.
科研通智能强力驱动
Strongly Powered by AbleSci AI