Amino‐λ3‐iodane‐Enabled Electrophilic Amination of Arylboronic Acid Derivatives

Abstract In this report, we describe the use of amino‐λ 3 ‐iodanes in the electrophilic amination of arylboronic acids and boronates. Iodine(III) reagents with transferable amino groups, including one with an NH 2 group, were synthesized and used in the amination, allowing the synthesis of a wide range of primary and secondary (hetero)arylamines. Mechanistic studies by DFT calculations indicate that the reaction proceeds through an electrophilic amination process from a tetravalent borate complex with a B−N dative bond.