亲电胺化
胺化
电泳剂
化学
试剂
硼
氨基酸
组合化学
有机化学
碘
功能群
催化作用
生物化学
聚合物
作者
Kensuke Kiyokawa,Kazuki Kawanaka,Satoshi Minakata
标识
DOI:10.1002/anie.202319048
摘要
In this report, we describe the use of amino‐λ3‐iodanes in the electrophilic amination of arylboronic acids and boronates. Iodine(III) reagents with transferable amino groups, which includes one with an NH2 group, were synthesized and used in the amination, allowing the synthesis of a wide range of primary and secondary (hetero)arylamines. Mechanistic studies by DFT calculations indicate that the reaction proceeds through an electrophilic amination process from a tetravalent borate complex with a B−N dative bond.
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