An organic trimer molecule with carbon black as an active material for supercapacitor applications

Quinone-based organic molecules show promise as electrode active materials for supercapacitor applications due to their reversible redox activity, high theoretical capacitances, low cost, nontoxicity, and renewability. The use of quinone containing molecules in supercapacitor applications faces challenges due to their low electrical conductivity and their high solubility in aqueous electrolytes that results in low cycling stability. This work addresses these limitations by proposing a novel quinone-composed material, N,N′-bis(2-anthra-quinone)]-perylene-3,4,9,10- tetracarboxydiimide (PDI-DAQ), as an organic molecule electrode for supercapacitors. PDI-DAQ was composited with a low-cost carbon substrate, Ketjenblack carbon black (CB), and demonstrated a specific capacitance of up to 318.6 F g −1 at 5 mV s −1 in 1 M H 2 SO 4 electrolyte at an optimized mass ratio of 1:1 (PDI-DAQ to CB). This material had a capacity retention of 61.2 % after 10,000 cycles at 100 mV s −1 . Ultimately, PDI-DAQ as a supercapacitor material demonstrates the performance advantages of covalently bonding redox-active quinone molecules and preparing a PDI-DAQ/CB OME through a simple preparation process. • Developed PDI-DAQ OME showcasing high redox activity and stability. • Achieved 53.8 % higher capacitance, up to 375 F g −1 over non-covalent quinones. • Combined PDI-DAQ with carbon black for better conductivity and charge transfer. • OME retained 61.2 % capacitance after 10,000 cycles in 1 M H 2 SO 4 . • Identified future research into capacitance loss mechanisms and optimization.