Recent Progress of Bismuth Effect on All‐Inorganic Lead‐Free Metal Halide Derivatives: Crystals Structure, Luminescence Properties, and Applications

Abstract Bismuth (Bi 3+ )‐included lead‐free metal halide (LFMH) materials attract much attention in lighting, display, photodetectors, X‐ray detectors, and photovoltaic fields, due to the tunable luminescence and optoelectronic performance in response to crystal and electronic structure, morphology, and particle sizes. This review summarizes Bi 3+ ‐included LFMH materials about their preparation approach, crystal and electronic structure properties, luminescence performance, and emerging applications. Notably, Bi 3+ ions not only can act as framework cation to construct stable LFMH structure, but can also incorporate into LFMH materials as activators or sensitizers to generate remarkable luminescence tuning and band engineering. The Bi 3+ effect on the luminescence and optoelectronic properties of LFMH materials, including, promotion of exciton localization, enhancement of light absorption in near‐ultraviolet region, action as sensitizer ions to transfer energy to rare earth or transition metal ions and emission of highly‐efficient light is systematically summarized. The proposed structure‐luminescence relationship offers guidance for the optimization of current Bi 3+ ‐included LFMH materials and the exploitation of new LFMH derivatives.