催化作用
法拉第效率
循环伏安法
氧化还原
碳纤维
化学
电催化剂
可逆氢电极
铜
电化学
无机化学
材料科学
电极
工作电极
有机化学
物理化学
复合材料
复合数
作者
Yuting Liu,Hua Liu,Cheng Wang,Yali Wang,Jia‐Xing Lu,Huan Wang
标识
DOI:10.1016/j.elecom.2023.107474
摘要
It is particularly desirable for the development of carbon utilization technologies to synthesize multicarbon products (C2+) from the electrochemical CO2 reduction reaction (CO2RR). In this work, Cu/Cu2O(X) catalysts (where X = I, Br, Cl) for selective electroreduction of CO2 to C2+ were reconstructed via cyclic voltammetry on carbon paper. The Faradaic efficiency (FE) for C2+ (C2H4, C2H5OH, C3H8OH) production over Cu/Cu2O(Cl), Cu/Cu2O(Br) and Cu/Cu2O(I) reached 31%, 34% and 58%, respectively, at a potential of −0.76 V vs. the reversible hydrogen electrode (RHE). The Cu+ and Cu0 species obtained from the reconstruction of Cu/CuX are primarily responsible for the high C2+ producing activity.
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