超顺磁性
纳米复合材料
材料科学
正硅酸乙酯
磁铁矿
傅里叶变换红外光谱
化学工程
溶胶凝胶
透射电子显微镜
纳米颗粒
磁性纳米粒子
Zeta电位
涂层
纳米技术
磁化
冶金
工程类
物理
磁场
量子力学
作者
Mitra Helmi Rashid Farimani,N. Shahtahmasebi,Mahmood Rezaee Roknabadi,Narjes Ghows,A. Kazemi
标识
DOI:10.1016/j.physe.2013.04.032
摘要
This paper describes a simple way for the coating of magnetite nanoparticles (MNPs) with amorphous silica. First, MNPs were synthesized by controlled co-precipitation technique under N2 gas and then their surface was modified with trisodium citrate in order to achieve particles with improved dispersibility. Afterward, magnetite-silica core/shell nanocomposites were prepared by a sol–gel approach, using magnetic fluid including electrostatically stabilized MNPs as seeds. The prepared samples were characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, zeta potential analysis and vibrating sample magnetometer (VSM) in order to study their structural and magnetic properties. FT-IR and XRD results imply that resultant nanocomposites are consisted of two compounds; Fe3O4 and SiO2 and TEM images confirm formation of their core/shell structure. TEM images also show increase in silica shell thickness from ∼5 to ∼24 nm with increase in amount of tetraethyl orthosilicate (TEOS) used during the coating process from 0.1 to 0.3 mL. Magnetic studies indicate that Fe3O4 nanoparticles remain superparamagnetic after coating with silica although their Ms values are significantly less than pristine MNPs. These core/shell nanocomposites offer a high potential for different biomedical applications due to having superparamagnetic property of magnetite and unique properties of silica.
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