预聚物
三羟甲基丙烷
结晶度
差示扫描量热法
材料科学
聚氨酯
TMPTA公司
玻璃化转变
甲苯二异氰酸酯
动态力学分析
高分子化学
异佛尔酮二异氰酸酯
二醇
热稳定性
异氰酸酯
多元醇
甲苯
化学工程
六亚甲基二异氰酸酯
共聚物
化学
复合材料
聚合物
有机化学
丙烯酸酯
工程类
物理
热力学
作者
Xiang Lu,Jintao Huang,Guangjian He,Li Yang,Ning Zhang,Yongqing Zhao,Jinping Qu
摘要
Cross-linked poly(butylene succinate) (PBS) was prepared by the reactions of the end hydroxyl groups of PBS with toluene diisocyanate and trimethylolpropane (TDI–TMP) polyurethane prepolymer at the processing temperature. The effects of varied TDI–TMP prepolymers on properties such as mechanical properties, thermal properties, dynamic mechanical properties, and crystal morphology were investigated. The results indicated that TDI–TMP prepolymer could cross-link PBS with high efficiency. The gel fraction of the cross-linked PBS increased with the content of TDI–TMP prepolymer, and the melt flow index of PBS decreased. Differential scanning calorimetry and dynamic mechanical analysis revealed that the crystallization temperature and glass transition temperature increased with the content of the TDI–TMP prepolymer, while the melting points and degree of relative crystallinity decreased. The cross-linked PBS also showed improved tensile properties, impact properties, thermal stability, and dynamic mechanical p...
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