Hydrological Controls on Drip Water δ 18 O Heterogeneity: A 4‐Year Monitoring Study in Remi Cave, Southern China

喀斯特 地下水补给 大气降水 水文学(农业) 亚热带 环境科学 地质学 土壤水分 混流 渗透(HVAC) 降水 稳定同位素比值 洞穴 斯佩莱奥瑟姆 δ18O 地表水 含水层 蒸散量 同位素特征 空间变异性 中国南方 地下水 包气带 石笋 季风 蓄水 同位素分析 滴灌 δ13C 季节性 土层 大气科学
作者
Shuyan Li,Yunxia Li,Wenyan Zhao,Zhimao Ye,Lin Zhao,Zhongwei Shen,Lidan Liu,Jiantao Cao,Zhiguo Rao
出处
期刊:Hydrological Processes [Wiley]
卷期号:40 (10)
标识
DOI:10.1002/hyp.70741
摘要

ABSTRACT Understanding how stable water isotopes are modified during percolation through the soil‐epikarst‐bedrock continuum is a fundamental challenge in karst hydrology, particularly in subtropical monsoon regions with heterogeneous infiltration dynamics. This study presents a four‐year (December 2020–December 2024) isotopic monitoring dataset from Remi Cave (southern China), including three precipitation sites (P1–P3), two soil water depths (50 and 95 cm), six drip sites (D1–D6), and two surface karst springs (R1 and R2). Our results show that: (1) Soil water, drip water, and spring water all plot close to the Local Meteoric Water Line but with lower slopes and intercepts, indicating evaporative fractionation during infiltration, with shallower soil water (50 cm) exhibiting stronger evaporation than deeper soil water (95 cm). (2) Considerable spatial heterogeneity exists among drip sites: D1, D2 and D5 preserve seasonal precipitation signals with the mean residence time (MRT) of approximately 1 year (~345–366 days), modulated by cave ventilation and drip‐rate variability. D3 and D4 show the most depleted δ 18 O values (−7.8‰ and −7.6‰, respectively) and negligible seasonal amplitudes, indicating that they are recharged primarily by wet‐season rainfall. D6 exhibits an MRT of ~73 days and shares similar isotopic characteristics with the two karst springs (MRT ~60–76 days), demonstrating rapid hydraulic connectivity through preferential fracture flow. (3) The marked offsets in δ 18 O among coeval drip sites within the same cave reveal that hydrological pathways, rather than climatic inputs alone, determine the isotopic composition of cave drip waters. These findings provide a quantitative framework for assessing water transit and recharge in subtropical karst. They also imply that site‐specific hydrology must be characterized before using speleothem δ 18 O for paleoclimate, and that ‘non‐replicated’ records may encode past recharge dynamics.
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