Photoinduced LMCT-Catalyzed Regioselective C(sp 3 )–H Functionalization of Boronates via a 1,2-Boryl Migration Pathway

)-H alkylation and arylation of unactivated alkyl boronates. This method enables a step-economical route to diverse functionalized boronates with good regioselectivity. Mechanistic studies suggest that the reaction proceeds through a sequential hydrogen atom transfer and 1,2-boryl migration pathway.