光催化
X射线光电子能谱
漫反射红外傅里叶变换
傅里叶变换红外光谱
扫描电子显微镜
粉末衍射
材料科学
吸附
结构精修
红外光谱学
化学
光化学
晶体结构
催化作用
结晶学
化学工程
物理化学
有机化学
工程类
复合材料
作者
Wendong Zhang,Yun Wang,Yi Liang,Ailin Jiang,Hao Gong,Xiao-Ying Tian,Wensheng Fu,Jing Liao,Peng Chen,Yingzhao Ma
标识
DOI:10.3389/fchem.2022.974907
摘要
In this work, a 4’-(4-cynaophenyl)-4,2’:6′,4-terpyridine supported Cu I MOFs photocatalyst ( Cu I MOF ) was applied to the photocatalytic CO 2 reduction for the first time. The micro-structural and physicochemical properties of the Cu I MOF were systematically studied by the powder X-ray diffraction (PXRD), Single crystal X-ray diffraction (SCXRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FT-IR), UV-Vis diffuse spectroscopy (UV-vis DRS), ns-level photoluminescence spectra (ns-level PL), Ultraviolet photoelectron spectroscopy (UPS), and N 2 adsorption-desorption test (BET-BJH). Moreover, the in situ diffuse reflectance infrared fourier transform spectroscopy ( in situ DRIFTS) was applied to investigate the adsorption and reaction intermediates of photocatalytic CO 2 reduction. As a result, Cu I MOF exhibited good performance and outstanding selectivity toward photocatalytic reduction of CO 2 to CO under full-spectrum and visible light illumination. Notably, 100% selective photocatalytic conversion of CO 2 to CO was achieved. Thus, the study presents the high selectivity and CO 2 reduction efficiency of Cu I MOF as a potential family of photocatalysts.
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