塔菲尔方程
异质结
材料科学
过电位
纳米棒
催化作用
氧化物
化学工程
金属
纳米结构
钼酸盐
光电子学
相(物质)
纳米技术
氢
电极
电化学
化学
物理化学
冶金
工程类
生物化学
有机化学
作者
Yangyang Feng,Ting Zhang,Jiahui Zhang,Hao Fan,Cheng He,Jiangxuan Song
出处
期刊:Small
[Wiley]
日期:2020-07-19
卷期号:16 (33)
被引量:113
标识
DOI:10.1002/smll.202002850
摘要
Metallic phase (1T) MoS2 has been regarded as an appealing material for hydrogen evolution reaction. In this work, a novel interface-induced strategy is reported to achieve stable and high-percentage 1T MoS2 through highly active 1T-MoS2 /CoS2 hetero-nanostructure. Herein, a large number of heterointerfaces can be obtained by interlinked 1T-MoS2 and CoS2 nanosheets in situ grown from the molybdate cobalt oxide nanorod under moderate conditions. Owing to the strong interaction between MoS2 and CoS2 , high-percentage of metallic-phase (1T) MoS2 of 76.6% can be achieved, leading to high electroconductivity and abundant active sites compared to 2H MoS2 . Furthermore, the interlinked MoS2 and CoS2 nanosheets can effectively disperse the nanosheets so as to enlarge the exposed active surface area. The near zero free energy of hydrogen adsorption at the heterointerface can also be achieved, indicating the fast kinetics and excellent catalytic activity induced by heterojunction. Therefore, when applied in hydrogen evolution reaction (HER), 1T-MoS2 /CoS2 heterostructure delivers low overpotential of 71 and 26 mV at the current density of 10 mA cm-2 with low Tafel slops of 60 and 43 mV dec-1 , respectively in alkaline and acidic conditions.
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