立体中心
化学
试剂
碳负离子
亲核细胞
催化作用
烷基
衍生化
有机化学
组合化学
对映选择合成
高效液相色谱法
作者
Rajender Nallagonda,Rashad R. Karimov
标识
DOI:10.1021/acscatal.0c04474
摘要
Nucleophilic addition of diborylalkyl reagents to N-alkyl or N-acylpyridinium and related heteroarenium salts has been developed as a key step for the synthesis of nonaromatic nitrogen heterocycles that contain contiguous stereogenic centers. Derivatization of the dihydropyridine products for the synthesis of tetrahydropyridines and piperidines have also been described.
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