有机溶剂
木质素
解聚
化学
木质纤维素生物量
产量(工程)
纤维素
微量分析
有机化学
单体
催化作用
核化学
聚合物
材料科学
冶金
作者
Richa Chaudhary,Paresh L. Dhepe
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2019-04-23
卷期号:33 (5): 4369-4377
被引量:19
标识
DOI:10.1021/acs.energyfuels.9b00621
摘要
Lignin extraction from lignocellulosic biomass has attracted considerable attention for an alternative production of sustainable fuels and chemicals. We report the lignin isolation from coconut coir using Klason, organosolv, and soda methods and the depolymerization of isolated lignin to value-added chemicals using a solid base catalyst. The yield of isolated lignin by the Klason method was found to be about 4 to 6 times higher than that by other methods. The structure of isolated Klason lignin (CC-KL), organosolv lignin (CC-ORGL), and soda lignin (CC-SL) was studied using attenuated total reflection (ATR), NMR, microanalysis, and so forth. The monomer molecular formula derived from microanalysis suggested that coir lignin is rich in guaiacyl units. ATR and 13C NMR clearly indicate that CC-ORGL contains more C–C bonds compared to CC-KL and CC-SL. Subsequently, these isolated lignins were depolymerized over a solid base catalyst (NaX) under atmospheric pressure. CC-SL shows a high yield of aromatic products (28%) compared to CC-ORGL and CC-KL. In order to develop a sustainable future technology, one-pot depolymerization of coconut coir was performed which resulted in a high yield (64%) of aromatic products.
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