费托法
催化作用
钴
摩尔比
化学
锆
无机化学
化学工程
选择性
有机化学
工程类
作者
Jong Wook Bae,Seung-Moon Kim,Seon-Ju Park,Yun-Jo Lee,Kwang Ha,Ki‐Won Jun
标识
DOI:10.1016/j.catcom.2010.03.003
摘要
A novel doubly promoted Ru/Co/ZrP/SiO2 catalyst with zirconium–phosphorous species (ZrP) reveals high activity and stability on Fischer–Tropsch synthesis (FTS). The surface modification of SiO2 with ZrP species containing appropriate amount of phosphorous component, has an effect on the suppression of cobalt particle aggregation during FTS reaction. The spatial confinement of cobalt particles in ZrP matrix could be significantly enhanced when P/(Zr + P) molar ratio is around 0.13 (CoZrP(0.5)).
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