化学
磷酸二羟丙酮
分子筛
二羟丙酮
甲醛
催化作用
镍
多聚甲醛
单糖
水溶液
冷凝
磷酸盐
有机化学
甘油
物理
热力学
作者
Irina Delidovich,M. N. Timofeeva,A.Yu. Orlov,Valentina N. Panchenko,Zubair Hasan,Sung Hwa Jhung,Оxana P. Тaran,Valentin N. Parmon
摘要
Condensation of dihydroxyacetone with formaldehyde was found to be effectively catalyzed by nickel phosphate molecular sieves (VSB-5 and Fe–VSB-5) in neutral aqueous medium. In the presence of VSB-5 the main products are erythrulose and 3-pentulose, while Fe–VSB-5 favours the formation of only erythrulose.
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