纤维素
材料科学
壳聚糖
高碘酸盐
水溶液
尿素
溶解
吸附
化学
再生纤维素
核化学
高分子化学
有机化学
作者
Ung-Jin Kim,Hyeon Joo Kim,Joon Weon Choi,Satoshi Kimura,Masahisa Wada
出处
期刊:Cellulose
[Springer Nature]
日期:2017-10-14
卷期号:24 (12): 5517-5528
被引量:58
标识
DOI:10.1007/s10570-017-1528-y
摘要
Crosslinked cellulose-chitosan beads were obtained via dissolution-regeneration of cellulose and chitosan by a LiOH/urea aqueous solution, followed by the crosslinking of chitosan via dialdehyde cellulose (DAC). This crosslinking reaction involved the Schiff base formation between the aldehyde groups of DAC and the amino groups of chitosan and subsequent reduction. DAC was prepared through periodate oxidation of cellulose and solubilization in hot water at 100 °C for 1 h. Four grades of DAC-crosslinked cellulose-chitosan were prepared by controlling the amount of cellulose and chitosan. The DAC-crosslinked cellulose-chitosan showed higher stability in the pH range of 2–9 over a long-term 21-day test. Additionally, the DAC-crosslinked chitosan showed a higher bovine serum albumin adsorption capacity as a result of the increased amino group content due to the crosslinking between DAC and chitosan, which occurred at multiple points in spite of a lower degree in crosslinking.
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