This paper describes tribological experiments carried out with polyetheretherketone (PEEK), filled with carbon fibres and solid lubricants (polytetrafluoroethylene (PTFE), graphite or MoS 2 ), against steel discs. Oscillating sliding tests were performed in high vacuum environment in the temperature range between -40°C and +160°C. Results indicate that MoS 2 filled PEEK show the best tribological performance in vacuum. Particularly, in the lower temperature range and at higher loads the friction behaviour is improved by the MoS 2 content.