阻燃剂
极限氧指数
材料科学
埃洛石
热重分析
极限抗拉强度
X射线光电子能谱
复合材料
复合数
化学工程
拉曼光谱
傅里叶变换红外光谱
有机化学
化学
燃烧
工程类
烧焦
物理
光学
作者
Yanli Dou,Aixun Ju,Zheng Zhong,Yujia Huo,Weiguo Yao
出处
期刊:Materials
[MDPI AG]
日期:2024-02-05
卷期号:17 (3): 761-761
摘要
Unsaturated polyester resin (UPR) with excellent flame retardant is mainly obtained by adding large amounts of flame retardants, usually at the expense of mechanical properties. In this work, a reactive flame retardant containing phosphorus and nitrogen (DOPO-N) was successfully synthesized and incorporated in UPR as a crosslinker. The mechanical and flame-retardant properties of UPR composites were enhanced. UPR/30DOPO-N passed a UL-94 V-1 rating with a limiting oxygen index (LOI) of 30.8%. The tensile strength of UPR/30DOPO-N increased by 24.4%. On this basis, a small amount of modified HNTs (VHNTs) was added to further improve the flame-retardant properties of the composite. With the introduction of 3 wt% VHNTs, the composite passed the UL-94 V-0 rating. The peak of heat release rate (PHRR) and total heat release (THR) of it decreased by 60.7% and 48.3%, respectively. Moreover, the detailed flame-retarding mechanism of DOPO-N and VHNTs was investigated by thermogravimetric infrared spectroscopy (TG-IR), Raman spectra, and X-ray photoelectron spectroscopy (XPS). It was found that DOPO-N played a role in quenching the flame in the gas phase and cooperated with VHNTs to enhance the barrier effect in the condensed phase.
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