材料科学
阴极
电解质
氧气
兴奋剂
纳米棒
沉积(地质)
储能
纳米技术
化学工程
光电子学
电极
电气工程
功率(物理)
物理化学
热力学
物理
工程类
古生物学
有机化学
化学
生物
沉积物
作者
Zhao Wang,Yurou Wang,Yuxuan Lin,Gang Bian,Haiyang Liu,Xiang Li,Jun Yin,Jian Zhu
标识
DOI:10.1021/acsami.2c13030
摘要
Aqueous zinc-ion batteries (ZIBs) have gained wide attention for their low cost, high safety, and environmental friendliness in recent years. β-MnO2, a potential cathode material for ZIBs, has been restricted by its small channels for efficient charge storage. Herein, β-MnO2 nanorods with oxygen vacancies are fabricated by a K+-doping strategy to improve the performance of ZIBs. The assembled batteries exhibit a capacity of 468 mAh g-1, a power density of 2605 W kg-1, and an energy density of 179 Wh kg-1, which outperforms most reported ZIBs. Such a performance is owing to the synergistic combination of the oxygen vacancies in β-MnO2 and concurrent deposition of ε-MnO2 from Mn2+ in the electrolyte. Furthermore, superior cycling stability with negligible capacity decay in these batteries is demonstrated over 1000 cycles at a high current of 2 A g-1. This study reveals the importance of oxygen vacancies and Mn2+ deposition effect in understanding the mechanism of charge storage in MnO2-based ZIBs.
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