Novel polymer nanoparticles with core–shell structure for breaking asphaltenes-stabilized W/O and O/W emulsions

Hypothesis. The removal of stable water-in-oil (W/O) or oil-in-water (O/W) emulsions has been a challenging issue in chemical and oil industry for decades. Traditional demulsifiers were generally designed specifically for treating either W/O or O/W emulsions. A demulsifier that is effective for treating both types of emulsions will be highly desired. Experiments. Novel polymer nanoparticles (PBM@PDM) was synthesized as a demulsifier for treating both W/O and O/W emulsions prepared by toluene, water, and asphaltenes. The morphology and chemical composition of synthesized PBM@PDM were characterized. Demulsification performance and interaction mechanisms including interfacial tension, interfacial pressure, surface charge properties and surface forces were systematically studied. Findings. PBM@PDM could immediately prompt the coalescence of water droplets upon addition and effectively release the water in asphaltenes-stabilized W/O emulsion. In addition, PBM@PDM successfully destabilized asphaltenes-stabilized O/W emulsion. Not only could PBM@PDM substitute the asphaltenes adsorbed at the water-toluene interface, but they could also dominate the water-toluene interfacial pressure in competition with asphaltenes. The steric repulsion between interfacial asphaltene films could be suppressed in the presence of PBM@PDM. Surface charges significantly influenced the stability of asphaltenes-stabilized O/W emulsion. This work provides useful insights into the interaction mechanisms of asphaltene-stabilized W/O and O/W emulsions.