极化
材料科学
压电
偶极子
陶瓷
铁电性
极化(电化学)
铁电陶瓷
凝聚态物理
复合材料
光电子学
电介质
有机化学
化学
物理
物理化学
作者
Yuxin Jia,Huiqing Fan,Ao Zhang,Han Wang,Lin Lei,Qifeng Quan,Guangzhi Dong,Weijia Wang,Qiang Li
标识
DOI:10.1016/j.jeurceramsoc.2022.10.058
摘要
Lead-free relaxor ferroelectric (RFE) ceramics find application in a broad range of technological devices due to their large electrostrain. But few lead-free ceramics show electrostrain values of more than 1 %. Here, an extraordinary strategy to obtain giant electrostrain by manipulating defect dipoles in (Bi, Na)TiO3-BaTiO3-based RFE ceramics is developed, achieving a high electro-induced strain value of 1.68 %, with a corresponding effective piezoelectric coefficient (d*33) of 1965 pm/V. Furthermore, the effect of defect dipoles on RFE ceramics is discussed. The defects are pinned after poling, forming defect dipoles polarization (Pd) oriented along or close to the poling direction. Pd significantly promotes the transformation of polar nano regions to ferroelectric domains during strain-electric field (S-E) cycles, resulting in ultra-high electrostrain. This work proposes a detailed mechanism considering defect dipoles coupling in RFE ceramics and provides a promising paradigm for achieving high electrostrain, which could be applied in designing a wide range of functional ceramics.
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