聚吡咯
聚合
材料科学
聚合物
聚酯纤维
化学工程
导电聚合物
单体
高分子化学
吡咯
原位聚合
傅里叶变换红外光谱
复合材料
化学
有机化学
工程类
作者
Ankur Shukla,Dipayan Das,Kushal Sen
摘要
This article offers a fast and innovative process for carrying out in situ polymerization of pyrrole onto a polyester fabric. This process is based on electrically-assisted chemical vapor polymerization that takes around 180 s to produce an electroconductive fabric with a surface resistance of as low as 70 Ω. The ultrasonication carried out at 20 kHz frequency is quite effective in binding the polymer to the fabric. Fourier-transform infrared spectroscopy and X-ray diffraction studies confirm that the polymer formed is polypyrrole. The application of electric potential across an oxidant-enriched fabric results in polymer add-on of polypyrrole as high as 250%. The amount of polypyrrole formed and the surface resistance of the fabric are found to depend on the potential applied across the fabric. The concentrations of the oxidant and the dopant, the time of polymerization, and the rate of monomer vaporization are found to be critical in deciding the surface resistance of the fabric.
科研通智能强力驱动
Strongly Powered by AbleSci AI