Mechanically Robust and Electrically Stable High-Performance Triboelectric Nanogenerator Based on Fluffy-Free EC/Nylon-11 and PTFE/PVDF Nanofibers

Electrospun nanofiber (NF)-based triboelectric nanogenerators (TENGs) have attracted significant attention in recent years due to their high specific surface area, flexibility, and facile fabrication. However, these TENGs' triboelectric (TE) layers composed of electrospun NFs fail easily due to the poor mechanical properties and fluffy characteristics of the NFs. Herein, electropositive and electronegative TE layers based on ethylcellulose-coated nylon-11 (EC/nylon-11) NFs and polytetrafluoroethylene-coated poly(vinylidene fluoride) (PTFE/PVDF) NFs are prepared via electrospinning and postcoating processes. The obtained EC/nylon-11 and PTFE/PVDF NFs are fluffy-free and exhibit 12.26 and 20.33-fold enhancements of Young's modulus compared with those of pure nylon-11 and PVDF NFs, respectively. The optimized TENG exhibits not only superior performance, including an open-circuit voltage (V_OC) of 212 V, a short-circuit current (I_SC) of 18.5 μA, and a maximum power density of 1.76 W/m² but also excellent electrical durability for over 100,000 cycles. The TENG's capability is further demonstrated by continuously driving electronics for over 5 min and by being integrated into a self-powered sensor array of electric skin to detect different in vitro stimuli. This work provides an effective approach to obtaining mechanically robust and electrically stable NF-based high-performance TENGs, which may have potential applications in durable, wearable, and self-powered nanoelectronics.