Investigation of the Proton Exchange Membrane Fuel Cell System Cathode Exhaust Gas Composition Based on Test Bed Measurements

Proton exchange membrane fuel cells are gaining increasing importance in vehicle applications. The exhaust gas composition regarding the water and oxygen content and the mass flow are important parameters in fuel cell research (e.g., for designing the test bed, quantifying the hydrogen loss in the exhaust, performing experiments with air pollutants, and monitoring degradation). The exhaust gas composition is also important for vehicle applications (e.g., ensuring safe hydrogen levels in the exhaust). Performing direct measurements of the exhaust mass flow and the relative humidity is challenging due to the high-humidity environment. This article presents a mathematical thermodynamic model used to calculate the exhaust gas mass flow and relative humidity, validated by balancing the gas species composition between cathode inlet and exhaust and by using data measured at the fuel cell system test bed. Four calculation model variations and their analyses are discussed. Furthermore, the exhaust gas composition throughout the fuel cell system operating range is presented. The results of air pollutant experiments provide comprehensive examples for the application of the calculation model. These results demonstrate the suitability of the model for its application in fuel cell system research.