材料科学
层状结构
微型多孔材料
战术性
复合材料
聚丙烯
膜
摩尔质量分布
高分子化学
聚合物
化学工程
聚合
化学
工程类
生物化学
作者
Dahua Chen,Li Yin,Zhixiang Su,Jianhe Xie,Ruijie Xu,Caihong Lei
出处
期刊:Journal of Polymer Engineering
[De Gruyter]
日期:2023-09-27
卷期号:43 (9): 791-800
标识
DOI:10.1515/polyeng-2023-0118
摘要
Abstract Two isotactic polypropylene (iPP) resins with approximate weight-average molecular weight ( Mw ) and different molecular weight distribution ( MWD ) were chosen to prepare cast films by the melt-stretching method. The lamellar morphology and mechanical properties of the initial precursor films and stretched microporous membranes were characterized. It was found that PP1 resin with a broader MWD exhibits a higher relaxation time of around 5.5 s, a larger entanglement density of 24.7 mol/m 3 and fast crystalline ability. The lamellar lateral size, orientation degree and entanglement density of the corresponding cast film are significantly increasing, resulting in higher elastic recovery and more apparent strain-hardening behavior. The PP resin with broader MWD also benefits the pore formation, resulting in a larger pore size and better air permeability of the stretched microporous membrane.
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