Surface Activated Pyrolytic Carbon Black: A Dual Functional Sustainable Filler for Natural Rubber Composites

The significant rise in end-of-life tires (ELTs) globally poses immediate environmental and human health risks. Therefore, to promote ELTs recycling and to reduce tire industry carbon emissions, herein we present a facile approach for fine-tuning the interfacial interactions between pyrolytic carbon black (P-CB) obtained from ELTs and natural rubber (NR) matrix using phosphonium-based ionic liquid (PIL). The reinforcing effect of PIL-activated P-CB was studied by replacing the furnace-grade carbon black (N330-CB) with varying PIL and P-CB loadings. Adding PIL improved the filler dispersion and the cross-linking kinetics with a substantially reduced zinc oxide (ZnO) loading. Considering the cross-linking and viscoelastic properties, it was concluded that the composite, P-CB/N330-CB-PIL (1.5)+ZnO (1) with half substitution of N330-CB with P-CB synergistically works with 1.5 phr PIL and 1 phr of ZnO resulting in improved dynamic-mechanical properties with a minimal loss tangent value at 60 °C (tanδ=0.0689) and improved glass transition temperature (T_g =-38 °C) compared to control composite. The significant drop (~29 % lower) in tanδ could reduce fuel consumption and related CO₂ emissions. We envisage that this strategy opens an essential avenue for "Green Tire Technology" towards the substantial pollution abatement from ELTs and reduces the toxic ZnO.