电解质
溶解度
电池(电)
熔点
化学
电化学窗口
离子电导率
阳极
离子液体
无机化学
坩埚(大地测量学)
卤化物
热力学
物理化学
有机化学
电极
物理
计算化学
催化作用
功率(物理)
作者
Xiaojing Zhao,Yanqun Guo,Shicheng Lu,Yuzheng Hui,Linhan Yin,Youdi Zhang,Bao-rang Li,Xinpeng Guo,Xinqiao Wang
标识
DOI:10.1002/cphc.202300546
摘要
The advanced electrolyte of liquid metal battery should have low melting point, low ionic solubility, low viscosity, high electric and thermal conductivities, and a suitable density between anode and cathode for declining the operating temperature and realizing the goal of saving-energy. In this study, an excellent quaternary LiF-LiCl-LiBr-LiI (9.1:30.0:21.7:39.2) electrolyte is refined by using thermodynamic models to balance various properties of LiX (X=F, Cl, Br, I) and meet the requirement of advanced electrolyte of liquid metal battery. The refined properties of electrolyte correspond to 2.398 g/cm3 for density, 0.286 mol% for solubility, 4.486 Ohm-1 cm-1 for ionic conductivity, and 0.609 W m-1 for thermal conductivity. The measured melting point is 609.1 K, which is lower than the current operating temperature of 723K for the lithium-based liquid metal battery. The refined electrolyte consisted by quaternary halide molten-salt provides important references for preparing the advanced liquid metal battery.
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