显色的
过氧化氢
吸光度
化学
铁电性
检出限
纳米材料
光化学
催化作用
纳米颗粒
化学发光
分析物
材料科学
纳米技术
色谱法
有机化学
电介质
光电子学
作者
Dan Yang,Jijun Liu,Weiling Hu,Yu X,Huanhuan Chen,Yijuan Long,Huzhi Zheng
标识
DOI:10.1016/j.snb.2023.134170
摘要
The oxidase-mimicking activity of ferroelectric BaTiO3 nanoparticles (BTO NPs) is reported. In the absence of hydrogen peroxide or oxygen, BTO NPs catalyzed the oxidation of 3,3′,5,5′-tetramethylbenzidine (TMB) and other chromogenic substrates. The catalytic constant (Kcat) was eight times that of fluorescein and 104 times that of bovine serum albumin-protected Se nanozymes. In the mechanism of the chromogenic reaction catalyzed by BTO NPs, the intrinsic electric field of the ferroelectric BTO drove the separation of holes and electrons, and the separated carriers reacted with water to produce reactive oxygen species that oxidized the chromogenic substrates. The BTO NPs-TMB chromogenic system was used to detect glutathione, which restored the blue-colored oxidized TMB to its colorless initial state. There was a good linear relationship between the absorbance change and the GSH concentration over the range 0.50–20 μM, with a 0.2-μM limit of detection. This work not only proposed a new idea of screening and designing nanozymes from ferroelectric materials but also expand the application of ferroelectric nanomaterials to bio-detection.
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