Ether‐Free Alkaline Polyelectrolytes for Water Electrolyzers: Recent Advances and Perspectives

Abstract Anion exchange membrane (AEM) water electrolyzers (AEMWEs) have attracted great interest for their potential as sustainable, environmentally friendly, low‐cost sources of renewable energy. Alkaline polyelectrolytes play a crucial role in AEMWEs, determining their performance and longevity. Because heteroatom‐containing polymers have been shown to have poor durability in alkaline conditions, this review focuses on ether‐free alkaline polyelectrolytes, which are more chemically stable. The merits, weaknesses, and challenges in preparing ether‐free AEMs are summarized and highlighted. The evaluation of synthesis methods for polymers, modification strategies, and cationic stability will provide insights valuable for the structural design of future alkaline polyelectrolytes. Moreover, the in situ degradation mechanisms of AEMs and ionomers during AEMWE operation are revealed. This review provides insights into the design of alkaline polyelectrolytes for AEMWEs to accelerate their widespread commercialization.