材料科学
荧光粉
发光二极管
钙钛矿(结构)
光电子学
量子效率
近红外光谱
二极管
光电效应
光学
化学
结晶学
物理
作者
Wenqiang Tang,Dan Wu,Yu Xiao,Xinyong Dong,Yue Wang,Weina Zhou,Yifan Liu,Liangliang Zhang
标识
DOI:10.1002/adom.202202237
摘要
Abstract Near‐infrared (NIR) phosphor‐converted light‐emitting diodes (pc‐LEDs) are an emerging light source demanded for the miniaturization of NIR spectroscopy. However, the photoelectric efficiency and spectral properties of NIR pc‐LEDs are still very limited due to a lack of efficient broadband NIR phosphors with peak emission wavelength >850 nm. Here, a novel Cr 3+ ‐activated perovskite‐like Mg 4 Ta 2 O 9 phosphor is reported, which exhibits a broad NIR emission band peaking at 850 nm with a high internal (external) quantum efficiency of 72% (33.4%). The fabricated NIR pc‐LED shows a broad emission band covering the whole 700–1100 nm spectrum range with a photoelectric conversion efficiency of 22.1% at 10 mA. This work may provide a new paradigm for the discovery of Cr 3+ singly doped NIR phosphors with excellent performance.
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