析氧
材料科学
过电位
塔菲尔方程
煅烧
贵金属
分解水
纳米颗粒
纳米材料
化学工程
纳米技术
纳米线
纳米纤维
催化作用
金属
金属有机骨架
电催化剂
电化学
光催化
电极
化学
吸附
有机化学
冶金
物理化学
工程类
作者
Lei Wu,Qi-Shun Wang,Jian Li,Yan Liu,Yu Liu,Shuyan Song,Hongjie Zhang
出处
期刊:Small
[Wiley]
日期:2018-04-17
卷期号:14 (20)
被引量:115
标识
DOI:10.1002/smll.201704035
摘要
Abstract Metal–organic frameworks (MOFs) with tunable compositions and morphologies are recognized as efficient self‐sacrificial templates to achieve function‐oriented nanostructured materials. Moreover, it is urgently needed to develop highly efficient noble metal‐free oxygen evolution reaction (OER) electrocatalysts to accelerate the development of overall water splitting green energy conversion systems. Herein, a facile and cost‐efficient strategy to synthesize Co 9 S 8 nanoparticles‐embedded N/S‐codoped carbon nanofibers (Co 9 S 8 /NSCNFs) as highly active OER catalyst is developed. The hybrid precursor of core–shell ZIF‐wrapped CdS nanowires is first prepared and then leads to the formation of uniformly dispersed Co 9 S 8 /N, S‐codoped carbon nanocomposites through a one‐step calcination reaction. The optimal Co 9 S 8 /NSCNFs‐850 is demonstrated to possess excellent electrocatalytic performance for OER in 1.0 m KOH solution, affording a low overpotential of 302 mV to reach the current density of 10 mA cm −2 , a small Tafel slope of 54 mV dec −1 , and superior long‐term stability for 1000 cyclic voltammetry cycles. The favorable results raise a concept of exploring more MOF‐based nanohybrids as precursors to induce the synthesis of novel porous nanomaterials as non‐noble‐metal electrocatalysts for sustainable energy conversion.
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