材料科学
电解质
电池(电)
电化学
离子电导率
化学工程
锂(药物)
电极
电导率
离子液体
离子键合
储能
快离子导体
纳米技术
离子
有机化学
物理化学
催化作用
化学
工程类
内分泌学
物理
功率(物理)
医学
量子力学
作者
Ziqi Wang,Rui Tan,Hongbin Wang,Luyi Yang,Jiangtao Hu,Haibiao Chen,Feng Pan
标识
DOI:10.1002/adma.201704436
摘要
Abstract Solid‐state batteries (SSBs) are promising for safer energy storage, but their active loading and energy density have been limited by large interfacial impedance caused by the poor Li + transport kinetics between the solid‐state electrolyte and the electrode materials. To address the interfacial issue and achieve higher energy density, herein, a novel solid‐like electrolyte (SLE) based on ionic‐liquid‐impregnated metal–organic framework nanocrystals (Li‐IL@MOF) is reported, which demonstrates excellent electrochemical properties, including a high room‐temperature ionic conductivity of 3.0 × 10 ‐4 S cm ‐1 , an improved Li + transference number of 0.36, and good compatibilities against both Li metal and active electrodes with low interfacial resistances. The Li‐IL@MOF SLE is further integrated into a rechargeable Li|LiFePO 4 SSB with an unprecedented active loading of 25 mg cm ‐2 , and the battery exhibits remarkable performance over a wide temperature range from −20 up to 150 °C. Besides the intrinsically high ionic conductivity of Li‐IL@MOF, the unique interfacial contact between the SLE and the active electrodes owing to an interfacial wettability effect of the nanoconfined Li‐IL guests, which creates an effective 3D Li + conductive network throughout the whole battery, is considered to be the key factor for the excellent performance of the SSB.
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