Hydrothermal Synthesis of Band Gap-Tunable Oxygen-Doped g-C3N4 with Outstanding “Two-Channel” Photocatalytic H2O2 Production Ability Assisted by Dissolution–Precipitation Process

Here, band gap-tunable oxygen-doped graphitic carbon nitride (g-C 3 N 4 ) with outstanding “two-channel” photocatalytic H 2 O 2 production ability was prepared via hydrothermal treatment assisted by dissolution–precipitation process. XRD, N 2 adsorption, UV–Vis, Fourier-transform infrared spectra, SEM, electrochemical impedance spectra, XPS and photoluminescence were used to characterize the obtained catalysts. The photocatalytic H 2 O 2 production ability of as-prepared catalyst was investigated. The results show that oxygen doping not only changes the morphology of catalyst, decreases the band gap energy and promotes the separation efficiency of photogenerated electrons and holes, but also tunes the CB and VB potentials. As-prepared oxygen-doped g-C 3 N 4 displays a H 2 O 2 concentration of 3.8[Formula: see text]mmol[Formula: see text]L[Formula: see text], more than 7.6 times higher than that of neat g-C 3 N 4 . Because of the shift of CB and VB potentials, not only the CB electrons of oxygen-doped g-C 3 N 4 reduce O 2 to form H 2 O 2 , but also the VB holes can oxidize OH − to form [Formula: see text]OH, which subsequently react with each other to form H 2 O 2 . Such “two-channel pathway” causes the remarkably promoted H 2 O 2 production ability.