Enhanced Mechanic Strength and Thermal Conductivities of Mica Composites with Mimicking Shell Nacre Structure

As the main insulation of high-voltage motors, the poor mechanical and thermal conductivities of mica paper restrict the motor's technological advances. This paper prepared multilayer toughening mica composites with a highly ordered "brick-mud" stacking structure by mimicking the natural conch nacre structure. We investigated the mechanical, thermal, and breakdown properties by combined study of tensile strength, stiffness, thermal conductivity, and breakdown strength at varying mica and nanocellulose contents. The results show that thermal conductivity of the mica/chitosan composites were gradually enhanced with the increase in mica content and the composite shows the optimal synthetic performance at 50 wt% mica content. Further addition of the nanocellulose can extremely enhance the thermal conductivities of mica/chitosan composites. The composite with 5 wt% nanocellulose obtained the maximal thermal conductivity of 0.71 W/(m·K), which was about 1.7 times that of the mica/chitosan composite (0.42 W/(m·K)) and much higher than normal mica tape (0.20 W/(m·K)). Meanwhile, the breakdown strength and tensile strength of mica/chitosan/nanocellulose composite also demonstrated substantial improvement. The application of the mica/chitosan/nanocellulose composite is expected to essentially enhance the stator power density and heat dissipation ability of large-capacity generators and HV electric motors.